Cooperative gas adsorption without a phase transition in metal-organic frameworks
슈퍼관리자
2021-05-21
Cooperative gas adsorption without a phase transition in metal-organic frameworks
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Authors :
Joyjit Kundu, Jurgen F. Stilck, Jung-Hoon Lee, Jeffrey B. Neaton, David Prendergast, and Stephen Whitelam
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Journal :
Phys. Rev. Lett.
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Vol :
121
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Page :
015701
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Year :
2018
Abstract
Cooperative adsorption of gases by porous frameworks, which permits more efficient uptake and removal than the more usual noncooperative (Langmuir-type) adsorption, usually results from a phase transition of the framework. Here we show how cooperativity emerges in the class of metal-organic frameworks mmen-M2
